Heat Transport: What I Wrote So Far.

Don’t worry, The Subversive Elkement will publish the usual silly summer posting soon! Now am just tying up loose ends.

In the next months I will keep writing about heat transport: Detailed simulations versus maverick’s rules of thumb, numerical solutions versus insights from the few things you can solve analytically, and applications to our heat pump system.

So I checked what I have already written – and I discovered a series which does not show up as such in various lists, tags, categories:

[2014-12-14] Cistern-Based Heat Pump – Research Done in 1993 in Iowa. Pioneering work, but the authors dismissed a solar collector for economic reasons. They used a steady-state estimate of the heat flow from ground to the tank, and did not test the setup in winter.

Cistern-Based Water-Source Heat Pump System Design, 1993[2015-01-28] More Ice? Exploring Spacetime of Climate and Weather. A simplified simulation based on historical weather data – only using daily averages. Focus: Estimate of the maximum volume of ice per season, demonstration of yearly variations. As explained later (2017) in more detail I had to use information from detailed simulations though – to calculate the energy harvested by the collector correctly in such a simple model.

Simple simulations of volume of ice[2015-04-01] Ice Storage Challenge: High Score! Our heat pump created an ice cube of about 15m3 because we had turned the collector off. About 10m3 of water remained unfrozen, most likely when / because the ice cube touched ground. Some qualitative discussions of heat transport phenomena involved and of relevant thermal parameters.

Ice formation during the 'ice storage challenge'[2016-01-07] How Does It Work? (The Heat Pump System, That Is) Our system, in a slide-show of operating statuses throughput a typical year. For each period typical temperatures are given and the ‘typical’ direction of heat flow.

System in September - typical operations conditions[2016-01-22] Temperature Waves and Geothermal Energy. ‘Geothermal’ energy used by heat pumps is mainly stored solar energy. A simple model: The temperature at the surface of the earth varies sinusoidally throughout the year – this the boundary condition for the heat equation. This differential equation links the temporal change of temperature to its spatial variation. I solve the equation, show some figures, and check how results compare to the thermal diffusivity of ground obtained from measurements.

Measured 'wave' and propagation time[2016-03-01] Rowboats, Laser Pulses, and Heat Energy (Boring Title: Dimensional Analysis). Re-visiting heat transport and heat diffusion length, this time only analyzing dimensional relationships. By looking at the heat equation (without the need to solve it) a characteristic length can be calculated: ‘How far does heat get in a certain time?’

Temperature waves in ground - attenuation length of about 10 meters[2017-02-05] Earth, Air, Water, and Ice. Data analysis of the heating season 2014/15 (when we turned off the solar/air collector to simulate a harsher winter) – and an attempt to show energy storages, heat exchangers, and heat flows in one schematic. From the net energy ‘in the tank’ the contribution of ground can be calculated.

Energy storage, heat exchangers, heat flow[2017-02-22] Ice Storage Hierarchy of Needs. Continued from the previous post – bird’s eye view: How much energy comes from which sources, and which input parameters are critical? I try to answer when and if simple energy accounting makes sense in comparison to detailed simulations.

Hierarchy of needs - ambient energy in ice months[2017-05-02] Simulating Peak Ice. I compare measurements of the level in the tank with simulations of the evolution of the volume of ice. Simulations (1-minute intervals) comprise a model of the control logic, the varying performance factor of the heat pump, heat transport in ground, energy balances for the hot and cold tanks, and the heat exchangers connected in series.

Simulations of brine and tank temperature and volume of ice, based on system state in 1-minute intervals.Next episode? Most likely something ‘philosophical’ about these simulations …

Spheres in a Space with Trillions of Dimensions

I don’t venture into speculative science writing – this is just about classical statistical mechanics; actually about a special mathematical aspect. It was one of the things I found particularly intriguing in my first encounters with statistical mechanics and thermodynamics a long time ago – a curious feature of volumes.

I was mulling upon how to ‘briefly motivate’ the calculation below in a comprehensible way, a task I might have failed at years ago already, when I tried to use illustrations and metaphors (Here and here). When introducing the ‘kinetic theory’ in thermodynamics often the pressure of an ideal gas is calculated first, by considering averages over momenta transferred from particles hitting the wall of a container. This is rather easy to understand but still sort of an intermediate view – between phenomenological thermodynamics that does not explain the microscopic origin of properties like energy, and ‘true’ statistical mechanics. The latter makes use of a phase space with with dimensions the number of particles. One cubic meter of gas contains ~1025 molecules. Each possible state of the system is depicted as a point in so-called phase space: A point in this abstract space represents one possible system state. For each (point-like) particle 6 numbers are added to a gigantic vector – 3 for its position and 3 for its momentum (mass times velocity), so the space has ~6 x 1025 dimensions. Thermodynamic properties are averages taken over the state of one system watched for a long time or over a lot of ‘comparable’ systems starting from different initial conditions. At the heart of statistical mechanics are distributions functions that describe how a set of systems described by such gigantic vectors evolves. This function is like a density of an incompressible fluid in hydrodynamics. I resorted to using the metaphor of a jelly in hyperspace before.

Taking averages means to multiply the ‘mechanical’ property by the density function and integrate it over the space where these functions live. The volume of interest is a  generalized N-ball defined as the volume within a generalized sphere. A ‘sphere’ is the surface of all points in a certain distance (‘radius’ R) from an origin

x_1^2 + x_2^2 + ... + x_ {N}^2 = R^2

(x_n being the co-ordinates in phase space and assuming that all co-ordinates of the origin are zero). Why a sphere? Because states are ordered or defined by energy, and larger energy means a greater ‘radius’ in phase space. It’s all about rounded surfaces enclosing each other. The simplest example for this is the ellipse of the phase diagram of the harmonic oscillator – more energy means a larger amplitude and a larger maximum velocity.

And here is finally the curious fact I actually want to talk about: Nearly all the volume of an N-ball with so many dimensions is concentrated in an extremely thin shell beneath its surface. Then an integral over a thin shell can be extended over the full volume of the sphere without adding much, while making integration simpler.

This can be seen immediately from plotting the volume of a sphere over radius: The volume of an N-ball is always equal to some numerical factor, times the radius to the power of the number of dimensions. In three dimensions the volume is the traditional, honest volume proportional to r3, in two dimensions the ‘ball’ is a circle, and its ‘volume’ is its area. In a realistic thermodynamic system, the volume is then proportional to rN with a very large N.

The power function rN turn more and more into an L-shaped function with increasing exponent N. The volume increases enormously just by adding a small additional layer to the ball. In order to compare the function for different exponents, both ‘radius’ and ‘volume’ are shown in relation to the respective maximum value, R and RN.

The interesting layer ‘with all the volume’ is certainly much smaller than the radius R, but of course it must not be too small to contain something. How thick the substantial shell has to be can be found by investigating the volume in more detail – using a ‘trick’ that is needed often in statistical mechanics: Taylor expanding in the exponent.

A function can be replaced by its tangent if it is sufficiently ‘straight’ at this point. Mathematically it means: If dx is added to the argument x, then the function at the new target is f(x + dx), which can be approximated by f(x) + [the slope df/dx] * dx. The next – higher-order term would be proportional to the curvature, the second derivation – then the function is replaced by a 2nd order polynomial. Joseph Nebus has recently published a more comprehensible and detailed post about how this works.

So the first terms of this so-called Taylor expansion are:

f(x + dx) = f(x) + dx{\frac{df}{dx}} + {\frac{dx^2}{2}}{\frac{d^2f}{dx^2}} + ...

If dx is small higher-order terms can be neglected.

In the curious case of the ball in hyperspace we are interested in the ‘remaining volume’ V(r – dr). This should be small compared to V(r) = arN (a being the uninteresting constant numerical factor) after we remove a layer of thickness dr with the substantial ‘bulk of the volume’.

However, trying to expand the volume V(r – dr) = a(r – dr)N, we get:

V(r - dr) = V(r) - adrNr^{N-1} + a{\frac{dr^2}{2}}N(N-1)r^{N-2} + ...
= ar^N(1 - N{\frac{dr}{r}} + {\frac{N(N-1)}{2}}({\frac{dr}{r}})^2) + ...

But this is not exactly what we want: It is finally not an expansion, a polynomial, in (the small) ratio of dr/r, but in Ndr/r, and N is enormous.

So here’s the trick: 1) Apply the definition of the natural logarithm ln:

V(r - dr) = ae^{N\ln(r - dr)} = ae^{N\ln(r(1 - {\frac{dr}{r}}))}
= ae^{N(\ln(r) + ln(1 - {\frac{dr}{r}}))}
= ar^Ne^{\ln(1 - {\frac{dr}{r}}))} = V(r)e^{N(\ln(1 - {\frac{dr}{r}}))}

2) Spot a function that can be safely expanded in the exponent: The natural logarithm of 1 plus something small, dr/r. So we can expand near 1: The derivative of ln(x) is 1/x (thus equal to 1/1 near x=1) and ln(1) = 0. So ln(1 – x) is about -x for small x:

V(r - dr) = V(r)e^{N(0 - 1{\frac{dr}{r})}} \simeq V(r)e^{-N{\frac{dr}{r}}}

3) Re-arrange fractions …

V(r - dr) = V(r)e^{-\frac{dr}{(\frac{r}{N})}}

This is now the remaining volume, after the thin layer dr has been removed. It is small in comparison with V(r) if the exponential function is small, thus if {\frac{dr}{(\frac{r}{N})}} is large or if:

dr \gg \frac{r}{N}

Summarizing: The volume of the N-dimensional hyperball is contained mainly in a shell dr below the surface if the following inequalities hold:

{\frac{r}{N}} \ll dr \ll r

The second one is needed to state that the shell is thin – and allow for expansion in the exponent, the first one is needed to make the shell thick enough so that it contains something.

This might help to ‘visualize’ a closely related non-intuitive fact about large numbers, like eN: If you multiply such a number by a factor ‘it does not get that much bigger’ in a sense – even if the factor is itself a large number:

Assuming N is about 1025  then its natural logarithm is about 58 and…

Ne^N = e^{\ln(N)+N} = e^{58+10^{25}}

… 58 can be neglected compared to N itself. So a multiplicative factor becomes something to be neglected in a sum!

I used a plain number – base e – deliberately as I am obsessed with units. ‘r’ in phase space would be associated with a unit incorporating lots of lengths and momenta. Note that I use the term ‘dimensions’ in two slightly different, but related ways here: One is the mathematical dimension of (an abstract) space, the other is about cross-checking the physical units in case a ‘number’ is something that can be measured – like meters. The co-ordinate  numbers in the vector refer to measurable physical quantities. Applying the definition of the logarithm just to rN would result in dimensionless number N side-by-side with something that has dimensions of a logarithm of the unit.

Using r – a number with dimensions of length – as base, it has to be expressed as a plain number, a multiple of the unit length R_0 (like ‘1 meter’). So comparing the original volume of the ball a{(\frac{r}{R_0})}^N to one a factor of N bigger …

aN{(\frac{r}{R_0})}^N = ae^{\ln{(N)} + N\ln{(\frac{r}{R_0})}}

… then ln(N) can be neglected as long as \frac{r}{R_0} is not extreeeemely tiny. Using the same argument as for base e above, we are on the safe side (and can neglect factors) if r is of about the same order of magnitude as the ‘unit length’ R_0 . The argument about negligible factors is an argument about plain numbers – and those ‘don’t exist’ in the real world as one could always decide to measure the ‘radius’ in a units of, say, 10-30 ‘meters’, which would make the original absolute number small and thus the additional factor non-negligible. One might save the argument by saying that we would always use units that sort of match the typical dimensions (size) of a system.

Saying everything in another way: If the volume of a hyperball ~rN is multiplied by a factor, this corresponds to multiplying the radius r by a factor very, very close to 1 – the Nth root of the factor for the volume. Only because the number of dimensions is so large, the volume is increased so much by such a small increase in radius.

As the ‘bulk of the volume’ is contained in a thin shell, the total volume is about the product of the surface area and the thickness of the shell dr. The N-ball is bounded by a ‘sphere’ with one dimension less than the ball. Increasing the volume by a factor means that the surface area and/or the thickness have to be increased by factors so that the product of these factors yield the volume increase factor. dr scales with r, and does thus not change much – the two inequalities derived above do still hold. Most of the volume factor ‘goes into’ the factor for increasing the surface. ‘The surface becomes the volume’.

This was long-winded. My excuse: Also Richard Feynman took great pleasure in explaining the same phenomenon in different ways. In his lectures you can hear him speak to himself when he says something along the lines of: Now let’s see if we really understood this – let’s try to derive it in another way…

And above all, he says (in a lecture that is more about math than about physics)

Now you may ask, “What is mathematics doing in a physics lecture?” We have several possible excuses: first, of course, mathematics is an important tool, but that would only excuse us for giving the formula in two minutes. On the other hand, in theoretical physics we discover that all our laws can be written in mathematical form; and that this has a certain simplicity and beauty about it. So, ultimately, in order to understand nature it may be necessary to have a deeper understanding of mathematical relationships. But the real reason is that the subject is enjoyable, and although we humans cut nature up in different ways, and we have different courses in different departments, such compartmentalization is really artificial, and we should take our intellectual pleasures where we find them.

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Further reading / sources: Any theoretical physics textbook on classical thermodynamics / statistical mechanics. I am just re-reading mine.

You Never Know

… when obscure knowledge comes in handy!

You can dismantle an old gutter without efforts, and without any special tools:

Just by gently setting it into twisted motion, effectively applying ~1Hz torsion waves that would lead to fatigue break within a few minutes.

I knew my stint in steel research in the 1990s would finally be good for something.

If you want to create a meme from this and tag it with Work Smart Not Harder, don’t forget to give me proper credits.

Simulating Peak Ice

This year ice in the tank was finally melted between March 5 to March 10 – as ‘visual inspection’ showed. Level sensor Mr. Bubble was confused during the melting phase; thus it was an interesting exercise to compare simulations to measurements.

Simulations use the measured ambient temperature and solar radiation as an input, data points are taken every minute. Air temperature determines the heating energy needed by the house: Simulated heat load is increasing linearly until a maximum ‘cut off’ temperature.

The control logic of the real controller (UVR1611 / UVR16x2) is mirrored in the simulation: The controller’s heating curve determines the set temperature for the heating water, and it switches the virtual 3-way valves: Diverting heating water either to the hygienic storage or the buffer tank for space heating, and including the collector in the brine circuit if air temperature is high enough compared to brine temperature. In the brine circuit, three heat exchangers are connected in series: Three temperatures at different points are determined self-consistently from three equations that use underground tank temperature, air temperature, and the heat pump evaporator’s power as input parameters.

The hydraulic schematic for reference, as displayed in the controller’s visualization (See this article for details on operations.)

The Coefficient of Performance of the heat pump, its heating power, and its electrical input power are determined by heating water temperature and brine temperature – from polynomial fit curves to vendors’ data sheet.

So for every minute, the temperatures of tanks – hot and cold – and the volume of ice can be calculated from energy balances. The heating circuits and tap water consume energy, the heat pump delivers energy. The heat exchanger in the tank releases energy or harvests energy, and the collector exchanges energy with the environment. The heat flow between tank and ground is calculated by numerically solving the Heat Equation, using the nearly constant temperature in about 10 meters depth as a boundary condition.

For validating the simulation and for fine-tuning input parameters – like the thermal properties of ground or the building – I cross-check calculated versus measured daily / monthly energies and average temperatures.

Measurements for this winter show the artificial oscillations during the melting phase because Mr. Bubble faces the cliff of ice:

Simulations show growing of ice and the evolution of the tank temperature in agreement with measurements. The melting of ice is in line with observations. The ‘plateau’ shows the oscillations that Mr. Bubble notices, but the true amplitude is smaller:

2016-09 - 2017-03: Temperatures and ice formation - simulations.

Simulated peak ice is about 0,7m3 greater than the measured value. This can be explained by my neglecting temperature gradients within water or ice in the tank:

When there is only a bit of ice yet (small peak in December), tank temperature is underestimated: In reality, the density anomaly of water causes a zone of 4°C at the bottom, below the ice.

When the ice block is more massive (end of January), I overestimate brine temperature as ice has less than 0°C, at least intermittently when the heat pump is turned on. Thus the temperature difference between ambient air and brine is underestimated, and so is the simulated energy harvested from the collector – and more energy needs to be provided by freezing water.

However, a difference in volume of less than 10% is uncritical for system’s sizing, especially if you err on the size of caution. Temperature gradients in ice and convection in water should be less critical if heat exchanger tubes traverse the volume of tank evenly – our prime design principle.

I have got questions about the efficiency of immersed heat exchangers in the tank – will heat transfer deteriorate if the layer of ice becomes too thick? No, according also to this very detailed research report on simulations of ‘ice storage heat pump systems’ (p.5). We grow so-called ‘ice on coil’ which is compared to flat-plate heat exchangers:

… for the coil, the total heat transfer (UA), accounting for the growing ice surface, shows only a small decrease with growing ice thickness. The heat transfer resistance of the growing ice layer is partially compensated by the increased heat transfer area around the coil. In the case of the flat plate, on the contrary, also the UA-value decreases rapidly with growing ice thickness.

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For system’s configuration data see the last chapter of this documentation.

Mr. Bubble Was Confused. A Cliffhanger.

This year we experienced a record-breaking January in Austria – the coldest since 30 years. Our heat pump system produced 14m3 of ice in the underground tank.

The volume of ice is measured by Mr. Bubble, the winner of The Ultimate Level Sensor Casting Show run by the Chief Engineer last year:

The classic, analog level sensor was very robust and simple, but required continuous human intervention:

Level sensor: The old way

So a multitude of prototypes had been evaluated …

Level sensors: The precursors

The challenge was to measure small changes in level as 1 mm corresponds to about 0,15 m3 of ice.

Mr. Bubble uses a flow of bubbling air in a tube; the measured pressure increases linearly with the distance of the liquid level from the nozzle:

blubber-messrohr-3

Mr. Bubble is fine and sane, as long as ice is growing monotonously: Ice grows from the heat exchanger tubes into the water, and the heat exchanger does not float due to buoyancy, as it is attached to the supporting construction. The design makes sure that not-yet-frozen water can always ‘escape’ to higher levels to make room for growing ice. Finally Mr. Bubble lives inside a hollow cylinder of water inside a block of ice. As long as all the ice is covered by water, Mr. Bubble’s calculation is correct.

But when ambient temperature rises and the collector harvests more energy then needed by the heat pump, melting starts at the heat exchanger tubes. The density of ice is smaller than that of water, so the water level in Mr. Bubble’s hollow cylinder is below the surface level of ice:

Mr. Bubble is utterly confused and literally driven over the edge – having to deal with this cliff of ice:

When ice is melted, the surface level inside the hollow cylinder drops quickly as the diameter of the cylinder is much smaller than the width of the tank. So the alleged volume of ice perceived by Mr. Bubble seems to drop extremely fast and out of proportion: 1m3 of ice is equivalent to 93kWh of energy – the energy our heat pump would need on an extremely cold day. On an ice melting day, the heat pump needs much less, so a drop of more than 1m3 per day is an artefact.

As long as there are ice castles on the surface, Mr. Bubble keeps underestimating the volume of ice. When it gets colder, ice grows again, and its growth is then overestimated via the same effect. Mr. Bubble amplifies the oscillations in growing and shrinking of ice.

In the final stages of melting a slab-with-a-hole-like structure ‘mounted’ above the water surface remains. The actual level of water is lower than it was before the ice period. This is reflected in the raw data – the distance measured. The volume of ice output is calibrated not to show negative values, but the underlying measurement data do:

Only when finally all ice has been melted – slowly and via thermal contact with air – then the water level is back to normal.

In the final stages of melting parts of the suspended slab of ice may break off and then floating small icebergs can confuse Mr. Bubble, too:

So how can we picture the true evolution of ice during melting? I am simulating the volume of ice, based on our measurements of air temperature. To be detailed in a future post – this is my cliffhanger!

>> Next episode.

Where to Find What?

I have confessed on this blog that I have Mr. Monk DVDs for a reason. We like to categorize, tag, painstakingly re-organize, and re-use. This is reflected in our Innovations in Agriculture …

The Seedbank: Left-over squared timber met the chopsaw.

The Nursery: Rebirth of copper tubes and newspapers.

… as well as in my periodical Raking The Virtual Zen Garden: Updating collections of web resources, especially those related to the heat pump system.

Here is a list of lists, sorted by increasing order of compactification:

But thanks to algorithms, we get helpful advice on presentation from social media platforms: Facebook, for example, encouraged me to tag products in the following photo, so here we go:

“Hand-crafted, artisanal, mobile nursery from recycled metal and wood, for holding biodegradable nursery pots.” Produced without crowd-funding and not submitted to contests concerned with The Intersection of Science, Art, and Innovation.

Ice Storage Hierarchy of Needs

Data Kraken – the tentacled tangled pieces of software for data analysis – has a secret theoretical sibling, an older one: Before we built our heat source from a cellar, I developed numerical simulations of the future heat pump system. Today this simulation tool comprises e.g. a model of our control system, real-live weather data, energy balances of all storage tanks, and a solution to the heat equation for the ground surrounding the water/ice tank.

I can model the change of the tank temperature and  ‘peak ice’ in a heating season. But the point of these simulations is rather to find out to which parameters the system’s performance reacts particularly sensitive: In a worst case scenario will the storage tank be large enough?

A seemingly fascinating aspect was how peak ice ‘reacts’ to input parameters: It is quite sensitive to the properties of ground and the solar/air collector. If you made either the ground or the collector just ‘a bit worse’, ice seems to grow out of proportion. Taking a step back I realized that I could have come to that conclusion using simple energy accounting instead of differential equations – once I had long-term data for the average energy harvesting power of the collector and ground. Caveat: The simple calculation only works if these estimates are reliable for a chosen system – and this depends e.g. on hydraulic design, control logic, the shape of the tank, and the heat transfer properties of ground and collector.

For the operations of the combined tank+collector source the critical months are the ice months Dec/Jan/Feb when air temperature does not allow harvesting all energy from air. Before and after that period, the solar/air collector is nearly the only source anyway. As I emphasized on this blog again and again, even during the ice months, the collector is still the main source and delivers most of the ambient energy the heat pump needs (if properly sized) in a typical winter. The rest has to come from energy stored in the ground surrounding the tank or from freezing water.

I am finally succumbing to trends of edutainment and storytelling in science communications – here is an infographic:

Ambient energy needed in Dec/Jan/Fec - approximate contributions of collector, ground, ice

(Add analogies to psychology here.)

Using some typical numbers, I am illustrating 4 scenarios in the figure below, for a  system with these parameters:

  • A cuboid tank of about 23 m3
  • Required ambient energy for the three ice months is ~7000kWh
    (about 9330kWh of heating energy at a performance factor of 4)
  • ‘Standard’ scenario: The collector delivers 75% of the ambient energy, ground delivers about 18%.
  • Worse’ scenarios: Either collector or/and ground energy is reduced by 25% compared to the standard.

Contributions of the three sources add up to the total ambient energy needed – this is yet another way of combining different energies in one balance.

Contributions to ambient energy in ice months - scenarios.

Ambient energy needed by the heat pump in  Dec+Jan+Feb,  as delivered by the three different sources. Latent ‘ice’ energy is also translated to the percentage of water in the tank that would be frozen.

Neither collector nor ground energy change much in relation to the base line. But latent energy has to fill in the gap: As the total collector energy is much higher than the total latent energy content of the tank, an increase in the gap is large in relation to the base ice energy.

If collector and ground would both ‘underdeliver’ by 25% the tank in this scenario would be frozen completely instead of only 23%.

The ice energy is just the peak of the total ambient energy iceberg.

You could call this system an air-geothermal-ice heat pump then!

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Continued: Here are some details on simulations.